贵阳花溪区石灰土林地土壤重金属含量特征及其污染评价
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国家科技部公益性研究资助项目(2007415);国家野外科学观测研究站资助项目(20060515,20070822);国家林业局948资助项目(200372);国家林业局重点资助项目(200508,200611,200617,2007R23);湖南省科技厅重点资助项目(2006SK4059,2007SK4030)


Heavy metal concentrations and pollution assessment of limestone forests in Huaxi district, Guiyang City
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    摘要:

    选取贵阳市花溪区典型石灰土林地土壤作为研究对象,分析了林地石灰岩和土壤中7种重金属(Cu、Zn、Mn、Cd、Ni、Pb、Co)的含量特征,以贵州省土壤背景值和全国石灰(岩)土类背景值为评价标准进行林地土壤重金属污染评价和潜在生态风险评价。结果表明:林地石灰岩以Pb的平均含量(40.21mg·kg-1)最高,Zn的(5.78 mg·kg-1)最低,7种重金属平均含量高低顺序为:Pb>Ni>Mn>Co>Cu>Cd>Zn;林地土壤中以Mn的平均含量(451.16 mg·kg-1以上)最高,Cd的(2.87mg·kg-1以下)最低,7种重金属含量的变异系数在8.57%~63.10%之间,Zn的平均含量明显低于贵州省土壤背景值和全国石灰(岩)土类背景值,Cu、Mn、Cd、Pb、Ni、Co的平均含量高于或接近于贵州省土壤背景值和全国石灰(岩)土类背景值。Cu、Zn、Mn、Ni、Co,Ni与Pb,Cd与Pb,Cd与Co来源相同的可能性较大,而Cd与Cu、Ni,Pb与Mn、Cu、Co的来源不同;石灰土偏碱性,富含Ca、Mg元素,有利于重金属Cd、Pb的累积。单因子污染指数和多因子综合指数(内梅罗指数法)与Hakanson潜在生态危害指数的评价结果一致,林地土壤重金属综合污染指数在3.67以上,达到重污染程度,以Cd的污染指数(4.94以上)最高,污染程度最为严重,其次是Pb(1.82以上),Zn、Mn污染程度最低,林地土壤重金属潜在生态危害指数(RI)为173.75以上,为中度生态危害程度,产生最大生态危害的是Cd,其次是Pb、Ni、Co、Cu,危害程度最小的是Mn、Zn,在相同的成土母岩和人为活动影响下,无林地土壤重金属的综合污染指数和潜在生态危害指数均明显高于有林地。

    Abstract:

    The concentrations of heavy metals (Cu, Zn, Mn, Cd, Ni, Pb and Co) were measured in limestone forests in Huaxi district, Guiyang, and assessment of heavy metal pollution was conducted by comparisons of our results with the background values of heavy metals of limestone soils in both Guizhou Province and in China. The results showed that the abundance of heave metals in the limestone rocks was in the order Pb (40.21mg·kg-1) >Ni>Mn>Co>Cu>Cd>Zn (5.78mg·kg-1). In the limestone soils, Mn (> 451.16 mg·kg-1) had the highest concentration and Cd (< 2.87mg·kg-1) had the lowest one of all test metals, with variation coefficients ranged from 8.57% to 63.10% for the seven heavy metals. On average, the concentration of Zn (< 55.16 mg·kg-1) was significantly lower than the background values of heavy metals of limestone soils in Guizhou Province (82.40 mg·kg-1) andin China (110.20 mg·kg-1), respectively; while the contents of Cu、Mn、Cd、Pb、Ni、Co were higher than or similar with these background values. Correlation analyses showed that thefive heavy metals (Cu, Zn, Mn, Ni and Co) came from the same recourses, and so did of Ni and Pb,Cd and Pb,and Cd and Co. Because of limestone soils with high contents of Ca and Mg elements, Cd and Pb were accumulated in the study sites. Comprehensive pollution index indicated the forest-lands were seriously polluted by heavy metals, with the highest index value of Cd (> 4.94), next to Pb (> 1.82), and the lowest values of Zn and Mn. Ecological risk index showed that Cd had the highest potential to cause ecological damage in study area, followed by the order Pb > Ni > Co > Cu > Mn > Zn. Our results indicated that both comprehensive pollution index and ecological risk index were considerably higher in bare-lands than forest-lands.

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宁晓波,项文化*,方晰,闫文德,邓湘雯.贵阳花溪区石灰土林地土壤重金属含量特征及其污染评价.生态学报,2009,29(4):2169~2177

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